The Enthalpy of Formation of Magnesium Carbonate

 The Enthalpy of Creation of Magnesium Carbonate Article

The Enthalpy of Creation of Magnesium Carbonate

Simply by: Jessica Burns

T. A: Thomas

Lab Partner: Rebekah Melanson

Thursday Lab

Room 106

Biochemistry 1001-A

Due Date: Thursday Feb . 3rd 2011


The goal of this try things out was to decide the enthalpy of development of magnesium (mg) carbonate within a lab environment. This was carried out using a calorimeter, which was calibrated by adding a known volume of both equally hot and cold normal water. Following the adjusted of the calorimeter, HCl was placed into the empty calorimeter and then mixed with magnesium after which MgCO3 and the temperature adjustments were recorded. The heat shed by the hot water is hence equal to the warmth gained by the calorimeter. Experimentally, it is difficult to determine the standard enthalpy of creation directly, for that reason Hess' Legislation is used and the worth is determined indirectly using reactions for the organization of Mg2-, MgCO3, WATER and CO2. These experiments led to the determination which the enthalpy of formation of magnesium carbonate is -1087. 53 kJ which led to a percent error of 2. 2%.


Magnesium Carbonate, MgCO3, is a white sturdy that occurs the natural way as a mineral, as has a variety uses. MgCO3 is used in floor coverings, fireproofing, fireplace extinguishing disposition, cosmetics, dusting powder, as well as toothpaste. It can also be used like a smoke suppressant in plastic materials, a rewarding agent in neoprene rubberized, a drying out agent, and an ingredient in stand salt to continue to keep it free flowing (Magnesium Carbonate). The purpose of this experiment is perfect for one to have the ability to determine the standard enthalpy of formation of Magnesium Carbonate. Every substance and physical change is definitely accompanied by a difference in energy, which in turn occurs by means of heat. The warmth of a response, also referred to as the change in enthalpy, is denoted by the symbol H. The enthalpy of reaction is expressed since the heat volume that is progressed or absorbed when a single mole of the reactant can be converted to product. This is considered to get exothermic (-H) when temperature is misplaced to the environment, and endothermic (+H) once heat is definitely gained through the surroundings. In order to determine the enthalpy of formation of Magnesium Carbonate, one need to first determine the value of H for Magnesium using calorimetry. The next step will be to determine the significance of H for MgCO3, yet , since this can not be determined straight, we must gauge the H pertaining to the change reaction and after that change the indication. Since the H values pertaining to H2O and CO2 are taken from research values, Hf (MgCO3) can now be determined making use of the following four equations: Mg(s) + 2H+(aq) Mg2+(aq) & H2(g)

Mg2+(aq) + H2O(l) +CO2 (g) MgCO3(s) +2H+(aq) H2(g) + 1/2O2(g) H2O(l) C + O2(g) CO2(g) Using Hess' Law, these equations can be added to give the fresh value pertaining to Hf(MgCO3) with the following equation: Mg(s) + C + 3/2O2(g) MgCO3(s)

Hess' Legislation, a term coined in the Russian chemist and medical doctor Germain Hess, is a legislation that declares, " the enthalpy modify for a effect that is accomplished in a series of steps is equal to the sum from the enthalpy improvements for the person steps” (Hess' Law). The law states the energy change for any substance or physical procedure is in addition to the path taken from the initial to final express. Hess' Regulation allows for the enthalpy change for a reaction to be determined even when it can't be assess directly. This is done by performing basic algebraic operations based upon the chemical equation of reactions using previously determined values intended for the enthalpies of development (Hess' Law). As mentioned earlier on, determining H1 and H2 are done utilizing a process called calorimetry. Derived from the Latina word pasion (meaning heat) and the Greek work metry (meaning to measure), calorimetry is the science of calculating the heat of chemical...

References: Chemistry 1001 Manual. Attach Allison University, Sackville, D. B. (2011).

University of Waterloo,. " Hess ' Law. " The principle of conservation of energ. N. g., 2009. Web. 1 Feb 2011..

University of California. " Calorimetry. " Biochemistry. N. p., 2010. Web. 1 Feb 2011..

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